ASTM D 6800 Standard Practice for Preparation of Water Samples Using Reductive Precipitation Preconcentration Technique for ICP-MS Analysis of Trace Metals
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ASTM D 6800 Document Information:
Title
Standard Practice for Preparation of Water Samples Using Reductive Precipitation Preconcentration Technique for ICP-MS Analysis of Trace Metals
ASTM International
Publication Date:
May 10, 2002
Scope:
Toxic elements may be present in ambient waters and may enter
the food chain via uptake by plants and animals; the actual
concentrations of toxic metals are usually sub-ng/mL. The U.S. EPA
has published its Water Quality Standards in the U.S. Federal
Register 40 CFR 131.36, Minimum requirements for water quality
standards submission, Ch. I (7-1-00 Edition), see Annex, Table
A1.1. The U.S. EPA has also developed Method 1640 to meet these
requirements, see Annex, Table A1.2.
Inductively Coupled Plasma Mass Spectroscopy (ICPMS) is a
technique with sufficient sensitivity to routinely measure toxic
elements in ambient waters, both fresh and saline (Test Method D
5673). However saline and hard water matrices pose analytical
challenges for direct multielement analysis by ICP-MS at the
required sub-ng/mL levels.
This standard practice describes a method used to prepare water
samples for subsequent multielement analysis using ICP-MS. The
practice is applicable to seawater and fresh water matrices, which
may be filtered or digested. Samples prepared by this method have
been analyzed by ICP-MS for the elements listed in Annex, Table
A1.3).
This standard does not purport to address all of the safety
concerns, if any, associated with its use. It is the responsibility
of the user of this standard to establish appropriate safety and
health practices and determine the applicability of regulatory
limitations prior to use.
Keywords:
- ambient
- brackish
- brine
- elements
- estuarine
- inductively coupled plasma-mass spectrometry
- pre-concentration
- seawater
- water
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